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LIGHT AND THE ATOMby@halhellman

LIGHT AND THE ATOM

by Hal HellmanAugust 24th, 2023
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Since light waves have such high frequencies, a different mode of generation comes into play. We can no longer count on the controlled movement of free electrons outside atoms and molecules. Rather, light and all the radiations in the higher frequencies are generated by the movement of electrons inside atoms and molecules. Let us review momentarily the modern, albeit highly simplified, conception of an atom. Remember that no one has yet seen one. We describe the atom on the basis of how it acts, as well as how it reacts to things scientists do to it. For the present purpose, the best model we have of the atom is that of a miniature solar system, with a nucleus or heavy part at the center and a cloud of electrons dashing around the nucleus in fixed orbits.
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Lasers by Hal Hellman, is part of the HackerNoon Books Series. You can jump to any chapter in this book here. LIGHT AND THE ATOM

LIGHT AND THE ATOM

Since light waves have such high frequencies, a different mode of generation comes into play. We can no longer count on the controlled movement of free electrons outside atoms and molecules. Rather, light and all the radiations in the higher frequencies are generated by the movement of electrons inside atoms and molecules.


Let us review momentarily the modern, albeit highly simplified, conception of an atom. Remember that no one has yet seen one. We describe the atom on the basis of how it acts, as well as how it reacts to things scientists do to it.


For the present purpose, the best model we have of the atom is that of a miniature solar system, with a nucleus or heavy part at the center and a cloud of electrons dashing around the nucleus in fixed orbits.


The term “fixed orbits” is used advisedly.


Our planet moves in a certain orbit around the sun. If we attached a large enough rocket to the earth we theoretically could move it closer to or farther away from the sun. In the atom, we have learned, this cannot be done. An electron can only exist in one of a certain number of fixed orbits; different kinds of atoms have different numbers of orbits.


We might think in terms of an elevator that can only stop at the various floors of an apartment building. Each upper floor is like an orbit of the electron. But you get nothing for nothing in the world of physics, and just as it takes energy to raise an elevator to a higher floor, it takes energy to move an electron to an outer orbit.


Hence the atom is said to be raised to higher energy levels when an electron is nudged to an outer orbit. The energy input can be of many different kinds. Examples are heat, pressure, electrical current, chemical energy, and various forms of electromagnetic radiation. If too much energy is put into the elevator it goes flying out the roof. If too much energy is put into the atom, one or more of its electrons will go flying out of the atom. This is called ionization, and the atom, now minus one of its negative electrons and therefore positively charged, is called a positive ion.


But if the right amount of energy is put into the atom, one of its electrons will merely be raised to a higher energy level. Shown in Figure 9, for instance, are the ground state (Circle No. 1) and two possible higher energy levels. As you can see there are three possible transitions.



Figure 9 Schematic representation of the electron orbits and energy levels of an atom. Each circle represents a separate possible orbit and each arrow a possible energy level difference.


The higher energy levels are abnormal, or excited, states, however, and the electron will shortly fall back to its normal (ground state) orbit (assuming some other electron has not fallen into it first). In order for the electron to do this (go back to its normal orbit), it must give off the energy it has acquired. This it does in the form of electromagnetic radiation.


The energy difference between the two levels will determine what kind of radiation is emitted, for there is a direct correlation between energy and frequency. If the energy difference between the two levels is such that the frequency of emitted radiation is roughly between 10¹⁴ and 10¹⁵ cycles per second, we see the radiation as light. When more energy is added, the radiation emerges as ultraviolet or X rays. In other words the higher the energy difference, the higher the frequency, and vice versa. Thus it is that cosmic rays, with the highest frequencies known to man, can pass right through us as if we weren’t there.


This simple picture of energy levels and associated frequencies doesn’t quite hold for ordinary white light, however. Such light is generally produced by a process called incandescence, which results from the heating of a material until it glows. True, the atoms of the incandescent material are being raised to higher energy levels by chemical energy (as in fire), electricity (light bulb), or nuclear energy (the sun). In a hot solid, however, the explanation becomes more complicated. Many different electronic configurations are possible and the differences in energy among the various levels (which can be many more than the three shown in Figure 9) vary only slightly from one another. The result is a wide band of radiation.


Thus, while the incandescent electric bulb is a great advance over fire, it is still a very inefficient source of light. Because it depends upon incandescence, a considerable portion of the electrical input goes into the production of unwanted heat, for the bulb’s filament radiates in the infrared as well as the visible region.


For providing illumination, the fluorescent tube is far more efficient than the incandescent lamp: a 40-watt fluorescent tube gives as much light as a 150-watt incandescent light. This is because its radiation is more controlled, operating more in accord with our description of electronic energy levels. Hence more of its output is in the desired visual region of the spectrum.


In certain types of lighting, particular energy level changes may predominate, leading to the characteristic colors of neon tubes and vapor lamps. Although the resulting radiation bandwidth is narrow enough in these devices to appear as a definite color instead of the broad spectrum we know as white, it is still quite broad. In other words, the radiation is still frequency incoherent—and it is still spatially incoherent.


To understand this, let us return for a moment to the group of radio antennas we showed in Figure 8. All of them, you will recall, could be made to radiate in phase. In the production of light, however, each antenna is replaced by a single atom!


This creates two problems. First, because the energy stored in the atom is quite small, it comes out not as a continuous wave but as a tiny packet of radiation—a photon. It has an effect more like the hack of an ax than the buzz of a power saw.


Second, atoms are notoriously “individualistic”. When a batch of atoms in a material has been raised to higher energy levels there is no way to know in what order, or in what direction, they will release their energy.


This kind of process is called spontaneous emission, since each atom “makes up its own mind”. All we know is that within a certain period of time—a short period, to be sure—a certain percentage of these higher energy atoms will release their photons.



Figure 10 Ordinary light is a jumble of frequencies, directions, and phases.


What we have, then, is incoherent radiation—a jumble of frequencies (or colors), directions, and phases. Such light, symbolized in Figure 10, works well enough in lighting up this page, but is almost worthless as a carrier of information (and in other ways, as we shall see shortly). About the best that can be done with it is to turn it on and off in a sort of visual Morse code, which is exactly what is done on the blinker communication systems sometimes used for ship-to-ship communication.


In other words, ordinary light cannot be modulated as radio waves can.


It is of interest to note, however, that ordinary white light can be made coherent, to some extent, but at a very high cost in the intensity of the light. For example, we might first pass the light through a series of filters, each of which would subtract some portion of the spectrum, until only the desired wavelength came through. As can be seen in Figure 11, only a small fraction of the original light would be left.



Figure 11 Obtaining coherent radiation the hard way. Filters and pinhole block all but a small amount of the original radiation.


Incoherent

Filters

Coherent in time

Pinhole

Coherent in time and space


We would then have monochromatic (one color) light, which is temporally coherent radiation, but it would still be spatially incoherent. In our diagram, we show three monochromatic waves. If we then passed this light through a tiny pinhole as shown, most of these few remaining waves would be blocked; the ones that got through would be pretty much in step. (In a similar manner, a true point source of light would produce spatially coherent radiation; but, as in the process described here, there wouldn’t be very much of it.)


We have, finally, obtained coherent light.


The important thing about the laser is that, by its very nature, it produces coherent light automatically.


Now....



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This book is part of the public domain. Hal Hellman (2021). Laser. Urbana, Illinois: Project Gutenberg. Retrieved October 2022 https://www.gutenberg.org/cache/epub/65512/pg65512-images.html


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