The Story of Nuclear Energy: Nuclear Fission | New Elements

Worlds Within Worlds: The Story of Nuclear Energy, Volume 3 (of 3), by Isaac Asimov is part of HackerNoon’s Book Blog Post series. You can jump to any chapter in this book here. Volume III, NUCLEAR FISSION: New Elements

Enrico Fermi (left) and Niels Bohr discuss physics as they stroll along the Appian Way outside Rome in 1931.

NUCLEAR FISSION

New Elements

In 1934 Enrico Fermi began his first experiments involving the bombardment of uranium with neutrons—experiments that were to change the face of the world.

Fermi had found that slow neutrons, which had very little energy, were easily absorbed by atomic nuclei—more easily than fast neutrons were absorbed, and certainly more easily than charged particles were.

Often what happened was that the neutron was simply absorbed by the nucleus. Since the neutron has a mass number of 1 and an atomic number of 0 (because it is uncharged), a nucleus that absorbs a neutron remains an isotope of the same element, but increases its mass number.

For instance, suppose that neutrons are used to bombard hydrogen-1, which then captures one of the neutrons. From a single proton, it will become a proton plus a neutron; from hydrogen-1, it will become hydrogen-2. A new nucleus formed in this way will be at a higher energy and that energy is emitted in the form of a gamma ray.

Sometimes the more massive isotope that is formed through neutron absorption is stable, as hydrogen-2 is. Sometimes it is not, but is radioactive instead. Because it has added a neutron, it has too many neutrons for stability. The best way of adjusting the matter is to emit a beta particle (electron). This converts one of the neutrons into a proton. The mass number stays the same but the atomic number increases by one.

The element rhodium, for example, which has an atomic number of 45, has only 1 stable isotope, with a mass number of 103. If rhodium-103 (45 protons, 58 neutrons) absorbs a neutron, it becomes rhodium-104 (45 protons, 59 neutrons), which is not stable. Rhodium-104 emits a beta particle, changing a neutron to a proton so that the nuclear combination becomes 46 protons and 58 neutrons. This is palladium-104, which is stable.

Fermi’s laboratory in Rome in 1930.

As another example, indium-115 (49 protons, 66 neutrons) absorbs a neutron and becomes indium-116 (49 protons, 67 neutrons), which gives off a beta particle and becomes tin-116 (50 protons, 66 neutrons), which is stable.

There are over 100 isotopes that will absorb neutrons and end by becoming an isotope of an element one higher in the atomic number scale. Fermi observed a number of these cases.

Having done so, he was bound to ask what would happen if uranium were bombarded with neutrons. Would its isotopes also be raised in atomic number—in this case from 92 to 93? If that were so it would be very exciting, for uranium had the highest atomic number in the entire scale. Nobody had ever discovered any sample of element number 93, but perhaps it could be formed in the laboratory.

In 1934, therefore, Fermi bombarded uranium with neutrons in the hope of obtaining atoms of element 93. Neutrons were absorbed and whatever was formed did give off beta particles, so element 93 should be there. However, four different kinds of beta particles (different in their energy content) were given off and the matter grew very confusing. Fermi could not definitely identify the presence of atoms of element 93 and neither could anyone else for several years. Other things turned up, however, which were even more significant.

Before going on to these other things, however, it should be mentioned that undoubtedly element 93 was formed even though Fermi couldn’t clearly demonstrate the fact. In 1939 the American physicists Edwin Mattison McMillan (1907- ) and Philip Hauge Abelson (1913- ), after bombarding uranium atoms with slow neutrons, were able to identify element 93. Since uranium had originally been named for the planet, Uranus, the new element beyond uranium was eventually named for the planet Neptune, which lay beyond Uranus. Element 93 is therefore called “neptunium”.

Lise Meitner

Emilio Segrè

Edwin M. McMillan

Otto R. Frisch

Glenn T. Seaborg

Philip H. Abelson

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What happened was exactly what was expected. Uranium-238 (92 protons, 146 neutrons) added a neutron to become uranium-239 (92 protons, 147 neutrons), which emitted a beta particle to become neptunium-239 (93 protons, 146 neutrons).

In fact, neptunium-239 also emitted a beta particle so it ought to become an isotope of an element even higher in the atomic number scale. This one, element 94, was named “plutonium” after Pluto, the planet beyond Neptune. The isotope, plutonium-239, formed from neptunium-239, was only feebly radioactive, however, and it was not clearly identified until 1941.

The actual discovery of the element plutonium came the year before, however, when neptunium-238 was formed. It emitted a beta particle and became plutonium-238, an isotope that was radioactive enough to be easily detected and identified by Glenn Theodore Seaborg (1912- ), and his co-workers, who completed McMillan’s experiments when he was called away to other defense research.

Neptunium and plutonium were the first “transuranium elements” to be produced in the laboratory, but they weren’t the last. Over the next 30 years, isotopes were formed that contained more and more protons in the nucleus and therefore had higher and higher atomic numbers. At the moment of writing, isotopes of every element up to and including element 105 have been formed.

A number of these new elements have been named for some of the scientists important in the history of nuclear research. Element 96 is “curium”, named for Pierre and Marie Curie; element 99 is “einsteinium” for Albert Einstein; and element 100 is “fermium” for Enrico Fermi.

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Element 101 is “mendelevium” for the Russian chemist Dmitri Mendeléev, who early in 1869 was the first to arrange the elements in a reasonable and useful order. Element 103 is “lawrencium” for Ernest O. Lawrence. “Rutherfordium” for Ernest Rutherford has been proposed for element 104.

And “hahnium” for Otto Hahn (1879-1968), a German physical chemist whose contribution we will come to shortly, has been proposed for element 105.

Neptunium, however, was not the first new element to be created in the laboratory. In the early 1930s, there were still 2 elements with fairly low atomic numbers that had never been discovered. These were the elements with atomic numbers 43 and 61.

In 1937, though, molybdenum (atomic number 42) had been bombarded with neutrons in Lawrence’s laboratory in the United States. It might contain small quantities of element 43 as a result. The Italian physicist Emilio Segrè (1905- ), who had worked with Fermi, obtained a sample of the bombarded molybdenum and indeed obtained indications of the presence of element 43. It was the first new element to be manufactured by artificial means and was called “technetium” from the Greek word for “artificial”.

The technetium isotope that was formed was radioactive. Indeed, all the technetium isotopes are radioactive. Element 61, discovered in 1945 and named “promethium”, also has no stable isotopes. Technetium and promethium are the only elements with atomic numbers less than 84 that do not have even a single stable isotope.

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Isaac Asimov. 2015. Worlds Within Worlds: The Story of Nuclear Energy, Volume 3 (of 3). Urbana, Illinois: Project Gutenberg. Retrieved May 2022 from https://www.gutenberg.org/cache/epub/10616/pg10616-images.html

This eBook is for the use of anyone anywhere at no cost and with almost no restrictions whatsoever. You may copy it, give it away or re-use it under the terms of the Project Gutenberg License included with this eBook or online at www.gutenberg.org, located at https://www.gutenberg.org/policy/license.html.