IRIDESCENT CRYSTALS

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The principal subject of the lecture is the peculiar colored reflection observed in certain specimens of chlorate of potash. Reflection implies a high degree of discontinuity. In some cases, as in decomposed glass, and probably in opals, the discontinuity is due to the interposition of layers of air; but, as was proved by Stokes, in the case of chlorate crystals the discontinuity is that known as twinning. The seat of the color is a very thin layer in the interior of the crystal and parallel to its faces. The following laws were discovered by Stokes: (1) If one of the crystalline plates be turned round in its own plane, without alteration of the angle of incidence, the peculiar reflection vanishes twice in a revolution, viz., when the plane of incidence coincides with the plane of symmetry of the crystal. [Shown.] (2) As the angle of incidence is increased, the reflected light becomes brighter and rises in refrangibility. [Shown.] (3) The colors are not due to absorption, the transmitted light being strictly complementary to the reflected. (4) The colored light is not polarized. It is produced indifferently, whether the incident light be common light or light polarized in any plane, and is seen whether the reflected light be viewed directly or through a Nicol's prism turned in any way. [Shown.] (5) The spectrum of the reflected light is frequently found to consist almost entirely of a comparatively narrow band. When the angle of incidence is increased, the band moves in the direction of increasing refrangibility, and at the same time increases rapidly in width. In many cases the reflection appears to be almost total.